2. Bases Properties and Examples

Definitions of acids and bases

Acids and bases form complementary pairs, so their definitions need to be considered together. There are three common groups of definitons: the ArrheniusBrønsted-Lowry, and Lewis definitions, in order of increasing generality.

  • Arrhenius: According to this definition, an acid is a substance that increases the concentration of hydronium ion (H3O+) when dissolved in water, while bases are substances that increase the concentration of hydroxide ions (OH). This definition limits acids and bases to substances that can dissolve in water. Around 1800, many French chemists, including Antoine Lavoisier, incorrectly believed that all acids contained oxygen. Indeed the modern German word for Oxygen is Sauerstoff (lit. sour substance). English chemists, including Sir Humphry Davy at the same time believed all acids contained hydrogen. The Swedish chemist Svante Arrhenius used this belief to develop this definition of acid.
  • Brønsted-Lowry: According to this definition, an acid is a proton (hydrogen nucleus) donor and a base is a proton (hydrogen nucleus) acceptor. The acid is said to be dissociated after the proton is donated. An acid and the corresponding base are referred to as conjugate acid-base pairs. Brønsted and Lowry formulated this definition, which includes water-insoluble substances not in the Arrhenius definition.
  • Lewis: According to this definition, an acid is an electron-pair acceptor and a base is an electron-pair donor. (These are frequently referred to as “Lewis acids” and “Lewis bases,” and are electrophiles and nucleophiles, respectively, in organic chemistry; Lewis bases are also ligands in coordination chemistry.) Lewis acids include substances with no transferable protons (i.e. H+ hydrogen ions), such as iron(III) chloride, and hence the Lewis definition of an acid has wider application than the Brønsted-Lowry definition. The Lewis definition can also be explained with molecular orbital theory. In general, an acid can receive an electron pair in its lowest unoccupied orbital (LUMO) from the highest occupied orbital (HOMO) of a base. That is, the HOMO from the base and the LUMO from the acid combine to a bonding molecular orbital. This definition was developed by Gilbert N. Lewis.

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