3. Chemical Bonding

Ionic Bond and Covalent Bond

There are two major types of chemical bonding: ionic bonds and covalent bonds. An ionic bond is a bond that results from the electrostatic attraction (force) between ions of opposite charges. Ionic bonds apply to ionic compound, such as sodium chloride (NaCl).

In simple ionic compounds, the metal element loses valence electron(s) to form the cation and the non-metal element gains electron(s) to form the anion. With the proper number of electron(s) lost or gained, both the cation and the anion achieve a full outer shell that contains eight electrons, as in the following examples of Na+, Ca2, Cland O2. According to Lewis’s Theory, an atom is most stable if its outer shell is filled or contains eight electrons. This is also called the octet rule.

Na (atom) → Na+ + e                     Ca (atom) → Ca2++ 2e

Cl (atom) + e→ Cl                       O (atom) + 2e– → O2-

A covalent bond is a bond formed through the sharing of electron pairs between the two bonding atoms. The shared electron pairs are mutually attracted by the nuclei of both atoms. By sharing the electron pairs, both atoms also gain a filled outer shell, or an octet. Almost all of the bonds involved in organic compounds are covalent bonds.

Covalent bond can be non-polar or polar.

For covalent bonds formed between two identical atoms, the electron pairs are shared equally between the two nuclei. Electron density is distributed evenly through the bond, making the bond a non-polar bond. Examples include all homonuclear molecules, such as H-H, Cl-Cl, O=O, N≡N.

A polar covalent bond formed between a positive hydrogen atom and a negative chloride atom.
a nonpolar covalent bond and polar covalent bond

For heteronuclear bonds (the bond formed between two different atoms), the electron pairs are not shared evenly, and the bond is polar. The electron pairs are more attractedto the atom that has the stronger ability to pull the electron pairs towards itself. This ability is measured with electronegativity. The relative values of electronegativity (EN) are listed using the scale devised by Linus Pauling, as summarized in the following table:

The electronegativity increases as you go from bottom to top and left to right on the periodic table
Electronegativity Values in Pauling Scale

With the introduction to the concept of electronegativity, bond polarity can be represented with the electronegativity difference between the two bonding atoms, which is known as ΔEN. For non-polar bonds, ΔEN equals to zero, and for polar bonds, ΔEN is not zero. The greater the ΔEN, the more polar the bond is.

Leave a Reply

Your email address will not be published. Required fields are marked *